[RuCl(p-cymene)((S)-dtbm-segphos(regR))]Cl [RuCl(p-cymene)((S)-dtbm-segphos)]Cl
Chloro{(S)-(+)-5,5''-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4''-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride
CAS: 944451-33-6
Molecular Formula: C84H112Cl2O8P2Ru
[RuCl(p-cymene)((S)-dtbm-segphos(regR))]Cl [RuCl(p-cymene)((S)-dtbm-segphos)]Cl - Names and Identifiers
| Name | Chloro{(S)-(+)-5,5''-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4''-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride |
| Synonyms | [RUCL(P-CYMENE)((S)-DTBM-SEGPHOS)]CL (S)-RuCl[(p-cyMene)(DTBM-SEGPHOS)]Cl [RuCl(p-cymene)((S)-dtbm-segphos[R])]Cl [RuCl(p-cymene)((S)-dtbm-segphos(regR))]Cl [RuCl(p-cymene)((S)-dtbm-segphos(regR))]Cl [RuCl(p-cymene)((S)-dtbm-segphos)]Cl Chloro{(S)-(+)-5,5''-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4''-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride Chloro[(S)-(+)-5,5'-bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) Chloride Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-dtbm-segphos(R))]Cl |
| CAS | 944451-33-6 |
[RuCl(p-cymene)((S)-dtbm-segphos(regR))]Cl [RuCl(p-cymene)((S)-dtbm-segphos)]Cl - Physico-chemical Properties
| Molecular Formula | C84H112Cl2O8P2Ru |
| Molar Mass | 1483.73 |
| Melting Point | >100°C |
| Water Solubility | Insoluble in water |
| Appearance | Powder |
| Color | orange to brown |
| Storage Condition | 2-8°C |
| Sensitive | air sensitive |
[RuCl(p-cymene)((S)-dtbm-segphos(regR))]Cl [RuCl(p-cymene)((S)-dtbm-segphos)]Cl - Risk and Safety
| WGK Germany | 3 |
[RuCl(p-cymene)((S)-dtbm-segphos(regR))]Cl [RuCl(p-cymene)((S)-dtbm-segphos)]Cl - Introduction
Chloro{(S)-( )-5,5 "-bis[di(3,) phosphino]-4,4"-bi-1,3-benzodioxole (p-cymene)ruthenium(II) chloride is an organometallic compound. The following is a description of its nature, use, formulation and safety information:
Nature:
Chloro{(S)-(-5,5 "-bis[di(3,) phosphino]-4,4"-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride is a solid, usually yellowish crystalline. It is stable at room temperature, but decomposes at high temperatures. It has good solubility in common solvents.
Use:
Chloro{(S)-(5,5 ''-bis[di(3, 3) phosphino]-4,4''-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride are often used in organic synthesis reactions. It is an effective chiral catalyst for asymmetric synthesis, hydrogenation and gas-phase methane carboxylation.
Preparation Method:
Chloro{(S)-(5,5 "-bis[di(3,) phosphino]-4,4"-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride are prepared by a complicated method. A common method of preparation is to first synthesize {(S)-( )-5,5 "-bis [bis (3,5-di-tert-butyl-4-methoxyphenyl) phosphino]-4,4 '-bis-1,3-benzodioxin} and then to obtain the desired compound by reaction with p-toluene and ruthenium chloride.
Safety Information:
For specific safety information chloride Chloro{(S)-(-5,5 ''-phosphino [di(3,)'' bis]-4,4 bi-1,3-benzodioxole}(p-cymene)ruthenium(II), it is recommended to refer to the relevant safety data sheet for this compound. When handling this compound, follow appropriate laboratory safety practices and avoid contact with skin, eyes, and inhalation of its gases. Safety assessments need to be made on a case-by-case basis, including consideration of the potential risks of the compound in terms of toxicity, flammability and explosiveness.
Nature:
Chloro{(S)-(-5,5 "-bis[di(3,) phosphino]-4,4"-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride is a solid, usually yellowish crystalline. It is stable at room temperature, but decomposes at high temperatures. It has good solubility in common solvents.
Use:
Chloro{(S)-(5,5 ''-bis[di(3, 3) phosphino]-4,4''-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride are often used in organic synthesis reactions. It is an effective chiral catalyst for asymmetric synthesis, hydrogenation and gas-phase methane carboxylation.
Preparation Method:
Chloro{(S)-(5,5 "-bis[di(3,) phosphino]-4,4"-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride are prepared by a complicated method. A common method of preparation is to first synthesize {(S)-( )-5,5 "-bis [bis (3,5-di-tert-butyl-4-methoxyphenyl) phosphino]-4,4 '-bis-1,3-benzodioxin} and then to obtain the desired compound by reaction with p-toluene and ruthenium chloride.
Safety Information:
For specific safety information chloride Chloro{(S)-(-5,5 ''-phosphino [di(3,)'' bis]-4,4 bi-1,3-benzodioxole}(p-cymene)ruthenium(II), it is recommended to refer to the relevant safety data sheet for this compound. When handling this compound, follow appropriate laboratory safety practices and avoid contact with skin, eyes, and inhalation of its gases. Safety assessments need to be made on a case-by-case basis, including consideration of the potential risks of the compound in terms of toxicity, flammability and explosiveness.
Last Update：2024-04-09 15:18:01
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Product Name: Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl Visit Supplier Webpage Request for quotation
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